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By S. V. Babu, S. Danyluk, M. I. Krishnan, M. Tsujimura

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McGrath, J. E. J. Appl. Polym. Sci. 1985, 30, 2207-2224. 51. Newman, W. ; Glasser, W. G. Holzforschung 1985, 39, 345-353. 52. Lambuth, A. S. Patent 4 279 788, 1981. 53. ;Nae, N. ; Gillham, J. K. J. Appl. Polym. Sci.. 1984, 29, 3307-3327. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1989. ch005 G . G r a h a m A l l a n , J o n A. D a l a n , and N o r m a n C . Foster Department of Chemical Engineering and College of Forest Resources University of Washington Seattle, W A 98195 The high temperature phenolysis of a commercially available, spray-dried, spent ammonium sulfite liquor from the pulping of softwood has been investigated under both batch and continuous regimes as a route to a phenol substitute for use in phenol-formaldehyde resins.

W h e r e a s , the entropie factor requires t h e use o f low m o l e c u l a r weight f r a c t i o n s for u n i f o r m gel f o r m a t i o n , t h e e n t h a l p i c p a r a m e t e r necessitates c h e m i c a l m o d i f i c a t i o n . T h e t y p e o f m o d i f i c a t i o n needed depends o n the m e d i u m in which gel formation is performed. Examples o f improving the solubility a n d c o m p a t i b i l i t y w i t h various r e a c t i o n m e d i a are c i t e d . Literature Cited 1.

Tappi 1965,48,398. 10. Marton, J. In Lignins: Occurrence, Formation, Structure, and Reactions; Sarkanen K. ; Ludwig, C. ; Wiley-Interscience: New York, 1971; Chapter 16. 11. ; Lindeberg, O. Acta Chem. Scand. 1979, Β 3 3 , 580. 12. ; Yoon, B. ; Terashima, N. Mokuzai Gakkaishi 1980, 26, 421. 13. ; Falkehag, S. ; Adler, E. Adv. Chem. Ser. 1966, 5 9 , 125. 14. Nimz, H. H. : New York, 1983; Chapter 5. 15. Van der Klashorst, G. ; Strauss, H. F. Holzforschung 1986, 4 0 , 375; J. Poly. Sci. 1986, A 24, 2143.

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